Arrhenius Theory of Ionisation

IMPORTANT

Arrhenius Theory of Ionisation: Overview

This topic covers concepts such as Strong Electrolytes, Degree of Dissociation for Equilibrium Reactions, Arrhenius Theory for Dissociation/Ionisation of Electrolysis, and Factors Affecting Degree of Ionization.

Important Questions on Arrhenius Theory of Ionisation

MEDIUM
IMPORTANT

Colour of solution is one of the evidences of Arrhenius theory of electrolytic dissociation

HARD
IMPORTANT

Which of the given evidences are not in favour of Arrhenius theory of dissociation?

HARD
IMPORTANT

Explain the evidences of Arrhenius theory of electrolytic dissociation?

MEDIUM
IMPORTANT

Which of the given Factors does not Affecting Degree of Ionization of an electrolyte?

HARD
IMPORTANT

Explain the Factors Affecting Degree of Ionization of an electrolyte?

EASY
IMPORTANT

Aqueous solution of which of the following compounds is the best conductor of electric current?

HARD
IMPORTANT

The degree of dissociation of N2O4 according to the equation N2O42NO2 at 70°C and atmospheric pressure is 65.6%. Calculate the apparent molecular weight of N2O4 under the above conditions.

[Hint: N2O141-x2NO22x; approx molecular weight =92(1-x)+46(2x)1+x]

HARD
IMPORTANT

Which of the following statement(s) according to the Arrhenius equation is/are correct?

HARD
IMPORTANT

PCl5gPCl3 g+Cl2 g

The degree of dissociation of PCl5 at one atmosphere is 0.3. The pressure at which PCl5 is dissociated to 50% is nearly:

MEDIUM
IMPORTANT

Equilibrium A4(g)4Ag  is established in a close container. A very tiny pinhole is made and very-very little amount of equilibrium mixture (equilibrium not altered) is effused out, in which mass percentage of atomic A is 40%. Hence degree of dissociation of A4 is -

MEDIUM
IMPORTANT

For the equilibrium AB(g)A(g)+B(g), at a given temperature 13rd of AB is dissociated then PKp will be numerically equal to

(P is the total pressure of equilibrium mixture and KP is the equilibrium constant)

EASY
IMPORTANT

Which of the following salts will not undergo hydrolysis?

EASY
IMPORTANT

A weak monobasic acid is 1% ionised in 0.1 M solution at 25. The percentage of ionisation in its 0.025 M solution is

HARD
IMPORTANT

Rate of diffusion of ozonized oxygen is  0.4 5 times that of pure oxygen. What is the percent degree of association of oxygen assuming pure O2 in the sample initially?

EASY
IMPORTANT

At a certain temperature, 2 HI H 2 + I 2 , only 50% HI is dissociated at equilibrium. The equilibrium constant is:

MEDIUM
IMPORTANT

The ionization constant of phenol is 1.0 × 10-10 in 0.05 M solution of phenol . What will be its degree of ionization, if the solution is also 0.01 M in sodium phenolate?

EASY
IMPORTANT

Degree of dissociation of 0.1 N CH3COOH is (Dissociation constant =1×10-5)

MEDIUM
IMPORTANT

H + of 0.2 N CH 3 COOH which is 4% dissociated, is

HARD
IMPORTANT

The following gaseous equilibrium was obtained by heating 0.46 moles of A in a  5.0 L vessel. The equilibrium pressure at 300 K was 3 atm. The equilibrium pressure changed to 3.6 atm when the temperature was raised to 320 K. Calculate the percentage change in the degree of dissociation of A at 350 K with respect to that of A at 300 K.

AgBg+Cg

HARD
IMPORTANT

0.020 g of selenium vapour at equilibrium occupying a volume of 2.463 mL at 1atm and 2 7 C  . The selenium is in a state of equilibrium according to the reaction: 3Se2(g)Se6g
What is the degree of association of selenium? (Atomic weight of Se=79)